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Blue Vitriol : ウィキペディア英語版
Copper(II) sulfate

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Copper (II) sulfate, also known as cupric sulfate or copper sulphate, is the inorganic compound with the chemical formula CuSO4.
This salt exists as a series of compounds that differ in their degree of hydration. The anhydrous form is a pale green or gray-white powder, whereas the pentahydrate (CuSO4·5H2O), the most commonly encountered salt, is bright blue. Copper (II) sulfate exothermically dissolves in water to give the aquo complex ()2+, which has octahedral molecular geometry and is paramagnetic. Other names for copper(II) sulfate are "blue vitriol" and "bluestone".〔(【引用サイトリンク】Oxford University">Copper (II) sulfate MSDS )〕
==Preparation and occurrence==

Copper sulfate is produced industrially by treating copper metal with hot concentrated sulfuric acid or its oxides with dilute sulfuric acid. For laboratory use, copper sulfate is usually purchased. Copper sulfate can also be produced by slowly leaching low grade copper ore in air; bacteria may be used to hasten the process.
Commercial copper sulfate is usually about 98% pure copper sulfate, and may contain traces of water. Anhydrous Copper sulfate is 39.81 percent copper and 60.19 percent sulfate by mass, and in its blue, hydrous form, it is 25.47% copper, 38.47% sulfate (12.82% sulfur) and 36.06% water by mass. Four types of crystal size are provided based on its usage: large crystals (10-40mm), small crystals (2-10 mm), snow crystals (less than 2 mm), and windswept powder (less than 0.15 mm).
The anhydrous form occurs as a rare mineral known as chalcocyanite. The hydrated copper sulfate occurs in nature as chalcanthite (pentahydrate), and two more rare ones: bonattite (trihydrate) and boothite (heptahydrate).

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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